Synthesis of Functionalized Isoindoles by the Rhodium-Catalyzed Reaction of Cyanoformates with ortho-Borylbenzalacetone Derivatives
نویسندگان
چکیده
منابع مشابه
Rhodium-Catalyzed, Enantioselective Hydroacylation of ortho-Allylbenzaldehydes.
The development of a rhodium catalyst for endo- and enantioselective hydroacylation of ortho-allylbenzaldehydes is reported. A catalyst generated in situ from [Rh(COD)Cl]2, (R)-DTBM-SEGPHOS, and NaBARF promotes the desired hydroacylation reactions and minimizes the formation of byproducts from competitive alkene isomerization and ene/dehydration pathways. These rhodium-catalyzed processes gener...
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ژورنال
عنوان ژورنال: Bulletin of the Korean Chemical Society
سال: 2010
ISSN: 0253-2964
DOI: 10.5012/bkcs.2010.31.6.1461